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Reversible phase transitions in a buckybowl monolayer

Leo Merz1, Manfred Parschau, Laura Zoppi

  • 1Nanoscale Materials Science, Swiss Federal Laboratories for Materials Testing and Research (Empa), Uberlandstrasse 129, 8600 Dübendorf, Switzerland.

Angewandte Chemie (International Ed. in English)
|February 13, 2009
PubMed
Summary

Buckybowl molecules, specifically corannulene, form denser structures when cooled on copper surfaces. Upon heating, these molecules spread out, driven by increased entropy from surface vibrations.

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