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Updated: Jun 25, 2026

Preparing an Isotopically Pure 229Th Ion Beam for Studies of 229mTh
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Preparing an Isotopically Pure 229Th Ion Beam for Studies of 229mTh

Published on: May 3, 2019

Nanometric chemical clocks.

Jean-Sabin McEwen1, Pierre Gaspard, Thierry Visart de Bocarmé

  • 1Centre for Nonlinear Phenomena and Complex Systems, CP 231, Université Libre de Bruxelles, B-1050 Brussels, Belgium. jmcewen@ulb.ac.be

Proceedings of the National Academy of Sciences of the United States of America
|February 19, 2009
PubMed
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This summary is machine-generated.

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Catalytic oscillatory patterns emerge at the nanoscale on rhodium nanocrystals due to differing nanofacet properties. Surface anisotropy, not reaction-diffusion, drives self-organization in this nanoreactor system.

Area of Science:

  • Surface science
  • Nanocatalysis
  • Chemical kinetics

Background:

  • Nanostructured materials exhibit unique catalytic properties.
  • Oscillatory phenomena in chemical reactions are crucial for understanding complex systems.
  • Field emitter tips provide a unique platform for nanoscale surface studies.

Purpose of the Study:

  • To investigate the origin of catalytic oscillatory patterns at the nanoscale.
  • To explore the role of surface anisotropy in nanostructured catalytic behavior.
  • To characterize the self-organizational behavior of multifaceted nanostructured surfaces.

Main Methods:

  • Field ion microscopy combined with video techniques.
  • Chemical probing of a rhodium nanosized crystal (field emitter tip).

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  • Exposure to hydrogen and oxygen reactants.
  • Main Results:

    • Observed nanoscale catalytic oscillatory patterns on a rhodium tip.
    • Attributed oscillations to differing catalytic properties of exposed nanofacets.
    • Demonstrated the significant role of surface anisotropy in self-organization.

    Conclusions:

    • Surface anisotropy is a key factor in nanostructured surface self-organization.
    • Standard reaction-diffusion mechanisms are not the primary drivers of these oscillations.
    • The nanoreactor system allows for regular oscillations to emerge from molecular fluctuations.