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Theoretical investigation of dinitrosyl complexes in Cu-zeolites as intermediates in deNOx process

Angeles Pulido1, Petr Nachtigall

  • 1Institute of Organic Chemistry and Biochemistry, ASCR, v.v.i., Flemingovo nám. 2, 16610, Prague 6, Czech Republic.

Physical Chemistry Chemical Physics : PCCP
|February 19, 2009
PubMed

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Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
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