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Stability of [2]pseudorotaxanes templated through second-sphere coordination

Barry A Blight1, James A Wisner, Michael C Jennings

  • 1Department of Chemistry, The University of Western Ontario, 1151 Richmond Street, Chemistry Building, London, Ontario N6A 5B7, Canada.

Inorganic Chemistry
|February 25, 2009
PubMed
Summary

Researchers explored palladium complexes with pyridine ligands, discovering a linear relationship between ligand electronic effects and complexation strength in pseudorotaxane formation. This finding aids in designing novel molecular architectures.

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