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![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Preparation and structural characterization of molecular Al-O-Sn(II) and Al-O-Sn(IV) compounds
Sharanappa Nembenna1, Sanjay Singh, Anukul Jana
1Institut fur Anorganische Chemie, Universitat Gottingen, Tammannstrasse 4, 37077 Gottingen, Germany.
Abstract:
Reaction of the organoaluminum hydroxide LAl(Me)OH (1) with different stoichiometric ratios of the homoleptic Sn(II) amide, Sn[N(SiMe(3))(2)](2), produced the bimetallic and trimetallic oxygen bridged aluminum-tin compounds LAl(Me)(mu-O)Sn[N(SiMe(3))(2)] (2) and [LAl(Me)(mu-O)](2)Sn (3), respectively. The former compound exhibits an Al-O-Sn(II)-N core and the latter an Al-O-Sn(II)-O-Al skeleton. In addition, we obtained the [LAl(Me)(mu-O)SnPh(3)] (5) with Al-O-Sn(IV) core by the reaction of [L(Me)Al-O-Mg(THF)(2)N(SiMe(3))(2)] (4) with Ph(3)SnOH in a 1:1 molar ratio.
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