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Published on: October 31, 2019
Ambidextrous bend patterns in free-standing polar smectic- CP{F} films
Alexey Eremin1, Alexandru Nemeş, Ralf Stannarius
1Otto-von-Guericke-Universität Magdeburg, IEP, Department of Nonlinear Phenomena, Universitätsplatz 2, D-39016 Magdeburg, Germany.
Ferroelectric smectic films with bent molecules exhibit an unexpected striped pattern. This unique bend deformation arises from molecular structure, not chirality, challenging existing theories.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Liquid Crystals
Background:
- Bent-shaped molecules in ferroelectric smectic films can exhibit complex director configurations.
- Previous studies identified twist-bend instability in similar systems.
Purpose of the Study:
- To investigate the unusual ground state director behavior in ferroelectric smectic-CP{F} films.
- To understand the origin of the observed striped pattern and its relation to molecular properties.
Main Methods:
- Experimental observation of ferroelectric smectic-CP{F} films.
- Analysis of the c-director behavior and bend deformation patterns.
Main Results:
- The ground state director forms a striped pattern with alternating bend deformation, deviating from a uniform state.
- The sense of the bend deformation is independent of the molecular tilt (c-director) and bow (p-director) orientation.
- The observed pattern cannot be explained by spontaneous chiral symmetry breaking due to pre-defined film chirality.
Conclusions:
- The striped bend pattern in ferroelectric smectic films is an unusual phenomenon.
- Molecular structure and synclinic order play a crucial role in defining the film's chirality and director behavior.
- Further theoretical models are needed to fully describe the spontaneous formation of this ambidextrous bend pattern.
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