Chiral induction, memory, and amplification in porphyrin homoaggregates based on electrostatic interactions

Lixi Zeng1, Yujian He, Zhifeng Dai

  • 1College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences (GUCAS), Beijing, P.R. China.

Summary

Chiral amino acids induce supramolecular chirality in meso-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) aggregates. This chirality is memorized and amplified using poly(allylamine) [PAA] via electrostatic self-assembly, demonstrating a novel chiral memory strategy.

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