A note on the vibrational efficacy in molecule-surface reactions.

C Díaz1, R A Olsen

  • 1Gorlaeus Laboratories, Leiden Institute of Chemistry, Leiden University, Leiden, The Netherlands. cristina.diaz@uam.es

Summary

Vibrational efficacy, a measure of how molecular vibrations aid surface reactions, can exceed one. This challenges the belief that it is strictly an energy measure, revealing complex dynamics in molecule-surface interactions.

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