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Updated: Jun 24, 2026

Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Experimental electron density study of the Mg-Mg bonding character in a magnesium(I) dimer
Jacob Overgaard1, Cameron Jones, Andreas Stasch
1Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark. jacobo@chem.au.dk
Abstract:
Experimental charge density modeling of a magnesium dimer complex and subsequent topological analysis reveals the existence of a chemical bond between the two central Mg atoms. Analysis of the molecular system using the energy density, the source function, and several density profiles along the entire bond path portrays the bond as one between two monovalent Mg atoms containing significant covalent character.
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Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.