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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Synthesis of orthorhombic Mo-V-Sb oxide species by assembly of pentagonal Mo6O21 polyoxometalate building blocks
Masahiro Sadakane1, Keiko Yamagata, Katsunori Kodato
1Catalysis Research Center, Hokkaido University, N-21, W-10, Sapporo, 001-0021, Japan. sadakane09@hiroshima-u.ac.jp
Angewandte Chemie (International Ed. in English)
|March 19, 2009
Abstract:
Mix and match: The pentagonal [Mo(6)O(21)](n-) polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo-V-Sb oxide. The first single-crystal X-ray analysis of an orthorhombic Mo-V-based oxide, a promising catalyst for light alkane selective oxidation known as the "M1 phase", revealed the structure of the compound.

