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Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Unprecedented sulfone-functionalized metal-organic frameworks and gas-sorption properties

Eleftheria Neofotistou1, Christos D Malliakas, Pantelis N Trikalitis

  • 1Department of Chemistry, University of Crete, Voutes, 71003 Heraklion, Greece.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|March 21, 2009
PubMed

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Preparation and Reactions of Sulfides02:26

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.