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An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation
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Structural colored gels for tunable soft photonic crystals.

Mohammad Harun-Ur-Rashid1, Takahiro Seki, Yukikazu Takeoka

  • 1Department of Molecular Design and Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan.

Chemical Record (New York, N.Y.)
|March 24, 2009
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Summary

Chemically engineered porous gels exhibit tunable structural colors due to ordered structures and Bragg diffraction. These smart soft materials, fabricated using colloidal crystal templates, offer responsive photonic properties.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Optics

Background:

  • Ordered porous structures in chemical gels can be templated by colloidal crystals.
  • These structures exhibit structural color via Bragg diffraction, enabling tunable photonic properties.
  • N-isopropylacrylamide (NIPA) is a key thermosensitive monomer for fabricating such gels.

Purpose of the Study:

  • To review the synthesis of colloidal crystal templates for porous gels.
  • To discuss the fabrication of structural colored porous gels.
  • To highlight the applications of these smart soft materials as tunable photonic crystals.

Main Methods:

  • Utilizing closest-packed colloidal crystals as templates for creating ordered porous structures.
  • Employing N-isopropylacrylamide (NIPA) and other monomers to synthesize structural colored gels.
  • Investigating techniques for regulating structural colors in porous gels.

Main Results:

  • Periodically ordered interconnecting porous structures were successfully embodied in chemical gels.
  • The porous gels displayed structural color due to coherent Bragg optical diffraction.
  • Tunable structural colors were achieved by regulating gel properties.

Conclusions:

  • Porous gels with ordered structures offer responsive and tunable photonic properties.
  • These materials function as smart soft materials with potential applications in tunable photonic crystals.
  • The synthesis and application of structural colored porous gels represent a significant advancement in materials science.