Related Experiment Video
Updated: Jun 24, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Hydrogen bonding in protic ionic liquids: reminiscent of water
Koichi Fumino1, Alexander Wulf, Ralf Ludwig
1Institut für Chemie, Abteilung Physikalische Chemie, Universität Rostock, Dr.-Lorenz-Weg 1, 18051 Rostock, Germany.
Abstract:
Similarities and differences: Far-infrared spectra of protic ionic liquids could be assigned to intermolecular bending and stretching modes of hydrogen bonds. The characteristics of the low-frequency spectra resemble those of water. Both liquids form three-dimensional network structures, but only water is capable of building tetrahedral configurations. EAN: ethylammonium nitrate, PAN: propylammonium nitrate, DMAN: dimethylammonium nitrate.
Related Concept Videos
Hydrogen Bonds
Hydrogen Bonds
Intermolecular Forces
Intermolecular Forces
Aqueous Solutions and Heats of Hydration
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
Comparing Intermolecular Forces: Melting Point, Boiling Point, and Miscibility
Temporary attractive forces like dispersion are present in all molecules, whether they are polar or nonpolar. They...

