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Updated: Jun 24, 2026
07:14
Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Transformation of a layered zinc phosphite to a three-dimensional open-framework structure with intersecting 16- and
Zhien Lin1, Hari Pada Nayek, Stefanie Dehnen
1Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35043 Marburg, Germany.
Inorganic Chemistry
|March 25, 2009
Abstract:
A new layered zinc phosphite, H(2)tmdp x Zn(3)(HPO(3))(4) (tmdp = 4,4'-trimethylenedipiperidine), was prepared in a flux of phosphorous acid without the addition of water as a solvent. The compound could be transformed into a new three-dimensional open-framework zinc phosphite, Zn(2)(H(2)O)(4)(HPO(3))(2) x H(2)O, with intersecting 16- and 12-ring channels at room temperature.
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