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Chiral transfer in coordination complexes: towards molecular materials.
1Sciences Chimiques de Rennes, UMR 6226, CNRS-Université de Rennes 1, Campus de Beaulieu, Rennes Cedex, 35042, France. jeanne.crassous@univ-rennes1.fr
Chemical Society Reviews
|March 27, 2009
Summary
This review explores coordination complexes that efficiently transfer chirality, controlling molecular structure and function. These chiral materials are vital for applications in luminescence, sensing, and magnetism.
Area of Science:
- Coordination Chemistry
- Materials Science
- Stereochemistry
Background:
- Chirality is crucial for molecular function and properties.
- Controlling stereochemistry in coordination complexes is challenging.
- Chiral transfer in molecular assemblies is key for advanced materials.
Purpose of the Study:
- To review coordination complexes with efficient chiral transfer.
- To present general features controlling chirality transmission.
- To highlight applications in functional chiral materials.
Main Methods:
- Critical review of existing literature.
- Analysis of coordination complexes exhibiting chiral transfer.
- Categorization of materials based on function.
Main Results:
- Examples of efficient chiral transfer in metal centers and molecular assemblies.
- General principles governing chirality transmission are outlined.
- Diverse applications demonstrated, including luminescent materials, MOFs, sensors, and magnets.
Conclusions:
- Coordination complexes offer versatile platforms for chiral transfer.
- Understanding chirality transmission enables the design of functional materials.
- This field holds significant potential for developing advanced chiroptical and magnetic materials.
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