Two-dimensional numerical modeling of 90Sr transport in an unsaturated Chinese loess under artificial sprinkling

(90)Sr is a fission byproduct of uranium and plutonium, and it presents a major health problem in the environment. A field test on the transport of various radionuclides including (90)Sr in an unsaturated Chinese loess was conducted under artificial rain conditions from July 1997 to August 2000. The vertical concentration distribution of (90)Sr displayed an unusual profile of double concentration peaks, which were separated by a thin (0.7 cm) source layer. In order to interpret the double-peak concentration profile, the transport of (3)H and (90)Sr in the unsaturated Chinese loess under artificial sprinkling conditions was simulated using WATERM, a numerical code for simulating flow field, and NESOR, also a numerical code but for simulating nuclide migration. The models were able to adequately simulate the double-peak concentration profile. The observation suggested that the fine arenaceous quartz layer, though 0.7 cm thick, formed a capillary barrier together with the local loess, which prevented water from penetrating. A significant discrepancy was observed between the model-fitted distribution coefficient (K(d)) of (90)Sr and that determined from independent laboratory experiments, which can be attributed to a number of factors such as the capillary barrier effect, solution-to-solid ratio and soil water content. Therefore, when the model is used for predictive purposes where K(d) is used as an input parameter, K(d) must be determined under well controlled conditions by taking into account these factors as well as the heterogeneity in the field.