The colloidal suprastructure of smart microgels at oil-water interfaces
Bastian Brugger1, Stephan Rütten, Kim-Ho Phan
1Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, 52056 Aachen, Germany.
Angewandte Chemie (International Ed. in English)
|March 31, 2009
Abstract:
Oil on troubled waters: Stimuli-sensitive emulsions have been used to prepare temperature- and pH-responsive microgels. The emulsion stability at oil-water interfaces is not governed by the particle packing density, and structural changes induced by the interface lead to connections between the individual microgels (see picture; scale bar 1 microm), which behave very differently compared to solid-particle-stabilized emulsions.
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