Comparing various chiral dirhodium tetracarboxylates in the dirhodium method

Jens T Mattiza1, Nobuyuki Harada, Shunsuke Kuwahara

  • 1Institute of Organic Chemistry, Leibniz University Hannover, Hannover, Germany.

Chirality
|April 3, 2009
PubMed
Summary

Chiral ligands can be differentiated using three enantiopure dirhodium tetracarboxylates. The (S)-2-methoxy-2-(1-naphthyl) propionate and (S)-N-phthaloyl-(S)-tert.-leucinate complexes show varying effectiveness for different donor types.

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