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Lattice energy represents the energy released when gaseous cations and anions combine to form an ionic solid, reflecting the strength of electrostatic interactions within the crystal. This process is fundamentally governed by Coulombic attraction between oppositely charged ions, where the potential energy varies inversely with the interionic distance and directly with the product of ionic charges. As ions approach one another, the electrostatic energy becomes increasingly negative, indicating a...
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Published on: November 11, 2013

Lithium barium silicate, Li(2)BaSiO(4), from synchrotron powder data.

Jinyoung Kim1, Docheon Ahn, Chandramouli Kulshreshtha

  • 1Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea.

Acta Crystallographica. Section C, Crystal Structure Communications
|April 7, 2009
PubMed
Summary
This summary is machine-generated.

The crystal structure of lithium barium silicate (Li(2)BaSiO(4)) was determined using synchrotron radiation powder data. This hexagonal structure features unique (Li(6)SiO(13))(5-) units, offering insights into related silicate materials.

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Area of Science:

  • Solid-state chemistry
  • Crystallography
  • Materials science

Background:

  • Lithium silicates are crucial in various applications, including phosphors and ceramics.
  • Understanding the crystal structure of alkaline earth metal silicates is key to tuning their properties.
  • Previous studies have characterized related compounds like Li(2)SrSiO(4) and Li(2)CaSiO(4).

Purpose of the Study:

  • To determine the crystal structure of lithium barium silicate, Li(2)BaSiO(4).
  • To elucidate the structural building blocks and connectivity within Li(2)BaSiO(4).
  • To discuss the relationship between the structures of Li(2)BaSiO(4), Li(2)SrSiO(4), and Li(2)CaSiO(4) and their luminescence properties.

Main Methods:

  • Synthesis of Li(2)BaSiO(4) via high-temperature solid-state reaction.
  • Structure determination using synchrotron radiation powder diffraction data.
  • Analysis of crystallographic space group (P6(3)cm) and atomic positions.

Main Results:

  • Li(2)BaSiO(4) crystallizes in the hexagonal space group P6(3)cm.
  • The structure is characterized by (Li(6)SiO(13))(5-) units composed of interconnected tetrahedra.
  • These units connect via corner-sharing of tetrahedra along the [001] direction and within the (001) plane.

Conclusions:

  • The detailed crystal structure of Li(2)BaSiO(4) has been successfully elucidated.
  • The findings provide a structural basis for understanding the properties of lithium barium silicate.
  • The structural insights facilitate comparisons with related compounds, aiding in the design of materials with specific luminescence characteristics.