Related Experiment Video
Updated: Jun 24, 2026

12:56
Seeded Synthesis of CdSe/CdS Rod and Tetrapod Nanocrystals
Published on: December 11, 2013
Size dependence of molar absorption coefficients of CdSe semiconductor quantum rods
Ehud Shaviv1, Asaf Salant, Uri Banin
1Institute of Chemistry and the Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Jerusalem 91904, Israel.
Abstract:
Fundamental properties: The molar absorption coefficients of CdSe quantum rods are determined experimentally as a function of their dimensions (see figure). Far above the band gap a simple dependence on volume is seen. The behavior at the band gap manifests a concentration of oscillator strength with decreased diameter in agreement with strong quantum confinement behavior.
Related Concept Videos
Debye–Huckel–Onsager Conductance Equation
The Debye-Hückel-Onsager equation is a cornerstone of physical chemistry, providing a method to determine the molar conductance (Λm) and molar conductance at infinite dilution (Λ°m) for uni-univalent electrolytes.Uni-univalent electrolytes are electrolytes that dissociate in solution to produce one cation with a +1 charge and one anion with a –1 charge per formula unit.This equation addresses two crucial phenomena: the asymmetry effect and the electrophoretic effect. According to this equation,...
UV–Vis Spectroscopy: Beer–Lambert Law
The Beer-Lambert law describes the relationship between absorbance and concentration, which combines the principles established by scientists Johann Heinrich Lambert and August Beer. Lambert's law states that when light passes through a medium, the loss in intensity is directly proportional to the original intensity and the path length of the light. Beer's law proposed that the transmittance of a solution remains constant if the product of concentration and path length is constant. The modern...

