Related Experiment Video
Updated: Jun 23, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Anomalous diffusion as modeled by a nonstationary extension of Brownian motion
John H Cushman1, Daniel O'Malley, Moongyu Park
1Department of Earth and Atmospheric Sciences and Department of Mathematics, Purdue University, West Lafayette, Indiana 47907, USA. jcushman@purdue.edu
Abstract:
If the mean-square displacement of a stochastic process is proportional to t;{beta} , beta not equal1 , then it is said to be anomalous. We construct a family of Markovian stochastic processes with independent nonstationary increments and arbitrary but a priori specified mean-square displacement. We label the family as an extended Brownian motion and show that they satisfy a Langevin equation with time-dependent diffusion coefficient. If the time derivative of the variance of the process is homogeneous, then by computing the fractal dimension it can be shown that the complexity of the family is the same as that of the Brownian motion. For two particles initially separated by a distance x , the finite-size Lyapunov exponent (FSLE) measures the average rate of exponential separation to a distance ax . An analytical expression is developed for the FSLEs of the extended Brownian processes and numerical examples presented. The explicit construction of these processes illustrates that contrary to what has been stated in the literature, a power-law mean-square displacement is not necessarily related to a breakdown in the classical central limit theorem (CLT) caused by, for example, correlation (fractional Brownian motion or correlated continuous-time random-walk schemes) or infinite variance (Levy motion). The classical CLT, coupled with nonstationary increments, can and often does give rise to power-law moments such as the mean-square displacement.
Related Concept Videos
Protein Diffusion in the Membrane
Diffusion on Chromatography Columns
Longitudinal diffusion occurs when the solute molecules in the mobile phase diffuse from the more concentrated center of the chromatographic band to the more dilute regions on either side, both towards and against the flow direction. This...
Diffusion
Diffusion
Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion
Physiological Pharmacokinetic Models: Blood Flow-Limited Versus Diffusion-Limited Models

