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Updated: Jun 23, 2026

Hydrolysis of a Ni-Schiff-Base Complex Using Conditions Suitable for Retention of Acid-labile Protecting Groups
Published on: April 6, 2017
Monoanion BH4(-) can stabilize zwitterionic glycine with dihydrogen bonds
Shan Xi Tian1, Hai-Bei Li, Jinlong Yang
1Hefei National Laboratory for Physical Sciences at Microscale Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui 230026, China. sxtian@ustc.edu.cn
Abstract:
Unusual strength: In the complex glycine-BH(4)(-), unconventional dihydrogen bonds are predicted. An ultrashort dihydrogen bond B-H...H-N and a very strong interaction of about -41 kcal mol(-1)) are found in complex 3 (see structures), in which the zwitterionic glycine is stabilized with a big margin.
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