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Updated: Jun 23, 2026
Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
Kinetic versus thermodynamic isomers of the deltahedral cobaltadicarbaboranes
R Bruce King1, Ioan Silaghi-Dumitrescu, Ioana Sovago
1Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA. rbking@chem.uga.edu
Abstract:
Synthesis of the deltahedral cobaltadicarbaboranes CpCoC(2)B(n-3)H(n-1) (n = 9, 10, 11, 12) typically leads initially to kinetically stable isomers with energies up to approximately 20 kcal/mol above the lowest energy isomers. Pyrolyses of these originally produced isomers typically results in isomerization to give more thermodynamically stable isomers. In this connection the relative stabilities of the CpCoC(2)B(n-3)H(n-1) (n = 9, 10, 11, 12) isomers have been investigated using density functional theory. For CpCoC(2)B(n-3)H(n-1) (n = 9, 10, 11) the isomers with both carbon atoms at degree 4 vertices are predicted to have the lowest energies. For CpCoC(2)B(9)H(11) the icosahedron is by far the preferred polyhedron. Among the nine possible icosahedral CpCoC(2)B(9)H(11) isomers, the unique isomer with the carbon atoms in antipodal (para) positions is the global minimum. However, the four CpCoC(2)B(9)H(11) isomers with the two carbon atoms in mutual non-antipodal non-adjacent (meta) positions lie within approximately 5 kcal/mol of the global minimum. These theoretical results are in reasonable agreement with the extensive experimental work on pyrolysis of CpCoC(2)B(n-3)H(n-1) (n = 9, 10, 11, 12) derivatives, mainly in the group of Hawthorne and co-workers during the 1970s.
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