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A variational framework for nonlinear chemical thermodynamics employing the maximum energy dissipation principle
1Engineering Department, Faculty of Technology, De Montfort University, Leicester, U.K.
Abstract:
The maximum energy dissipation principle is employed to nonlinear chemical thermodynamics in terms of distance variable (generalized displacement) from the global equilibrium, applying the optimal control interpretation to develop a variational formulation. The cost-like functional was chosen to support the suggestion that such a formulation corresponds to the maximum energy dissipation principle. Using this approach, the variational framework was proposed for a nonlinear chemical thermodynamics, including a general cooperative kinetics model. The formulation is in good agreement with standard linear nonequilibrium chemical thermodynamics.
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