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Updated: Jun 23, 2026

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Microwave spectrum of the argon-tropolone van der Waals complex
Wei Lin1, Wallace C Pringle, Stewart E Novick
1Department of Natural Sciences and Mathematics, University of Saint Mary, Leavenworth, Kansas 66048, USA.
Abstract:
The rotational spectrum of the argon-tropolone van der Waals complex in the ground vibrational state has been measured in the frequency range of 6-17 GHz using a pulsed-jet, Balle-Flygare-type Fourier transform microwave spectrometer. Eighty-six transitions for the complex (Ar-(12)C(7)H(6)(16)O(2)) were observed, assigned, and fit using a Watson A-reduction Hamiltonian giving the rotational and centrifugal distortion constants A = 1080.4365(3) MHz, B = 883.4943(3) MHz, C = 749.0571(2) MHz, Delta(J) = 2.591(2) kHz, Delta(JK) = -3.32(1) kHz, Delta(K) = 5.232(9) kHz, delta(J) = 0.944(1) kHz, and delta(K) = -0.028(8) kHz. The tunneling motion of the hydroxyl proton in the tropolone moiety is quenched in the ground electronic state by complexation with argon. The coordinates of the argon atom in the monomer's principal axis system are a = 0.43 A, b = 0.23 A, and c = 3.48 A.
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