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[Ring effect and correction studies while retrieving trace gas concentration with passive DOAS].

Ying-Hua Zhang1, Pin-Hua Xie, Fu-Qi Si

  • 1Key Laboratory of Environmental Optical & Technology, Anhui Institute of Optics & Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China. yinghuazhang2001@163.com

Guang Pu Xue Yu Guang Pu Fen Xi = Guang Pu
|May 19, 2009
PubMed
Summary
This summary is machine-generated.

Passive DOAS (Differential Optical Absorption Spectroscopy) measures trace gases using scattered sunlight. This study modifies the method to correct for the Ring effect, improving measurement precision for gases like NO2.

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Area of Science:

  • Atmospheric chemistry and spectroscopy
  • Remote sensing techniques
  • Environmental monitoring

Context:

  • Passive DOAS is a widely used technique for measuring atmospheric trace gases.
  • The accuracy of passive DOAS is significantly impacted by the Ring effect, caused by solar Fraunhofer lines.
  • This effect is particularly problematic for precise measurements of low-concentration gases.

Purpose:

  • To investigate the influence of the Ring effect on trace gas retrieval using passive DOAS.
  • To analyze the relationship between the Ring effect and the solar zenith angle.
  • To develop and validate a modification to the passive DOAS method to mitigate the Ring effect.

Summary:

  • The study addresses the challenge of the Ring effect in passive DOAS measurements.
  • A novel modification is proposed, involving the selection of different Ring spectra based on the solar zenith angle.
  • The modified method was successfully applied to retrieve slant column densities (SCD) of NO2 over three stable days, demonstrating its feasibility.

Impact:

  • Improved accuracy and precision in trace gas concentration measurements using passive DOAS.
  • Enhanced reliability of atmospheric monitoring data, especially for pollutants at lower concentrations.
  • Potential for broader application of passive DOAS in environmental studies and air quality assessments.