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Updated: Jun 23, 2026

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
Unusual selectivity of a (pincer)Ni-hydride reacting with CO2
Matthew F Laird1, Maren Pink, Nikolay P Tsvetkov
1Department of Chemistry, Indiana University, Bloomington, IN, USA.
Abstract:
The reaction of (PNP)NiH, where PNP is ((t)Bu2PCH2SiMe2)2-N(-1), with CO2 occurs over a period of hours at 25 degrees C to form (POP)NiH(NCO), which involves transposition of the initial amide nitrogen and one oxygen of CO2.
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