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Synthesis and microcontact printing of dual end-functionalized mucin-like glycopolymers for microarray applications
Kamil Godula1, David Rabuka, Ki Tae Nam
1Department of Chemistry, University of California and The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
Angewandte Chemie (International Ed. in English)
|May 30, 2009
Abstract:
Click to view: Glycopolymers can be used to display glycans on microarrays in native-like architectures. The structurally uniform alkyne-terminated mucin mimetic glycopolymers (see picture; TR = fluorophore) were printed on azide-functionalized chips by microcontact printing in the presence of a copper catalyst. The surface-bound glycopolymers bind lectins in a ligand-specific manner.
