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Conformer lifetimes of ethyl cyanoformate from exchange-averaged rotational spectra
1Department of Chemistry, University of California, Davis, Davis California 95616, USA.
Abstract:
Ethyl cyanoformate exists as a mixture of two conformers but displays three R-branch a-type band series in its rotational spectrum. Simulations with population fractions 0.37 at 210 K and 0.70 at 297 K undergoing conformer exchange with average conformer lifetimes,
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