Related Experiment Video
Updated: Jun 22, 2026

Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
Published on: July 9, 2015
Poly(o-phenylenediamine) submicrosphere-supported gold nanocatalysts: synthesis, characterization, and application in
1School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, Jiangsu, PR China.
Abstract:
A facile solution route was proposed for the successful synthesis of uniform poly(o-phenylenediamine) (PoPD) submicrospheres with an average diameter of 700 nm. Utilizing the reactivity of dedoped PoPD submicrospheres for gold salt HAuCl4, gold nanoparticles can be synthesized in the presence of PoPD without additional reductant for HAuCl4. Furthermore, PoPD submicrospheres with abundant amino groups and pi electrons in benzene rings on their surfaces can significantly stabilize gold nanoparticles, which will lead to the formation of PoPD submicrosphere-supported gold nanoparticles. Reaction conditions, such as addition of poly(vinylpyrrolidone) and concentration of HAuCl4, were found to affect the size of gold nanoparticles. Products were characterized by Fourier-transform infrared (FT-IR) and X-ray diffraction (XRD) spectroscopies. The synthesized PoPD submicrosphere-supported gold nanoparticles with different size were used to evaluate their catalytic performances for benzyl alcohol. Results revealed that PoPD submicrosphere-supported gold nanoparticles showed high yield and selectivity for benzyl alcohol to aldehyde conducted under air and in water media. The factors, such as catalyst size and amount, solvent, temperature, alkali type, and reaction time, were all systematically investigated to elucidate their effects on the yield and selectivity of catalytic benzyl alcohol reactions.
More Related Videos
11:16Preparation of Silver-Palladium Alloyed Nanoparticles for Plasmonic Catalysis under Visible-Light Illumination
Published on: August 18, 2020
05:34Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
Published on: December 16, 2019
Related Concept Videos
Reactions at the Benzylic Position: Oxidation and Reduction
Radical Oxidation of Allylic and Benzylic Alcohols
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Oxidation of Phenols to Quinones
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
Electrophilic Aromatic Substitution: Sulfonation of Benzene
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...