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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Published on: April 10, 2015

Reductive phosphine-mediated ligation of nitroxyl (HNO)

Julie A Reisz1, Erika B Klorig, Marcus W Wright

  • 1Department of Chemistry, Salem Hall, Box 7486, Wake Forest University, Winston-Salem, North Carolina 27109, USA.

Organic Letters
|June 5, 2009
PubMed
Summary

Nitroxyl (HNO) reacts with phosphines to form aza-ylides. These aza-ylides can then undergo Staudinger ligation, enabling new methods for detecting HNO in biological systems.

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