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Related Concept Videos

Molecular Spectroscopy: Absorption and Emission01:14

Molecular Spectroscopy: Absorption and Emission

Molecules possess discrete energy levels called quantum states. Unlike atoms, which have simpler energy levels, molecules possess additional rotational and vibrational energy levels. Each energy level is separated by an energy gap, with the gaps between adjacent electronic, vibrational, and rotational levels varying significantly. The three types of energy levels in a diatomic molecule are shown in Figure 1.
UV–Vis Spectroscopy of Conjugated Systems01:32

UV–Vis Spectroscopy of Conjugated Systems

Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
One of the factors influencing λmax is the extent of conjugation in the...
Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
UV–Vis Spectroscopy: Molecular Electronic Transitions01:16

UV–Vis Spectroscopy: Molecular Electronic Transitions

In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this process,...

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Related Experiment Video

Updated: Jun 22, 2026

Resonance Fluorescence of an InGaAs Quantum Dot in a Planar Cavity Using Orthogonal Excitation and Detection
12:57

Resonance Fluorescence of an InGaAs Quantum Dot in a Planar Cavity Using Orthogonal Excitation and Detection

Published on: October 13, 2017

Two-photon absorption in CdTe quantum dots.

Lázaro Padilha, Jie Fu, David Hagan

    Optics Express
    |June 6, 2009
    PubMed
    Summary
    This summary is machine-generated.

    We measured two-photon absorption (2PA) in Cadmium Telluride quantum dots (QDs). 2PA strongly depends on QD size, decreasing as dots get smaller. A model predicts 2PA spectra for various QD sizes.

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    Last Updated: Jun 22, 2026

    Resonance Fluorescence of an InGaAs Quantum Dot in a Planar Cavity Using Orthogonal Excitation and Detection
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    Area of Science:

    • Materials Science
    • Quantum Physics
    • Nanotechnology

    Background:

    • Two-photon absorption (2PA) is a nonlinear optical process with applications in imaging and materials processing.
    • Cadmium Telluride (CdTe) quantum dots (QDs) are semiconductor nanocrystals with tunable optical properties.

    Purpose of the Study:

    • To measure and analyze the frequency-dependent 2PA spectra of CdTe QDs in glass matrices.
    • To investigate the influence of QD size on 2PA properties.
    • To adapt and validate a theoretical model for predicting 2PA spectra.

    Main Methods:

    • Experimental measurement of degenerate and nondegenerate 2PA spectra of CdTe QDs of varying sizes.
    • Comparison of QD 2PA spectra with bulk CdTe.
    • Adaptation of a degenerate 2PA model using effective mass approximation for nondegenerate cases.

    Main Results:

    • 2PA in CdTe QDs is strongly size-dependent, decreasing with smaller QD size.
    • The adapted model accurately describes experimental 2PA data up to approximately 1.4 times the bandgap energy (Eg).
    • Normalization to dot volume did not eliminate the size dependence of 2PA.

    Conclusions:

    • The size-dependent 2PA behavior of CdTe QDs is a critical factor in their optical response.
    • The developed theoretical model provides a predictive tool for 2PA spectra of different sized CdTe QDs.
    • This research facilitates the design and application of QDs in nonlinear optical technologies.