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Updated: Jun 22, 2026

A Continuous-flow Photocatalytic Reactor for the Precisely Controlled Deposition of Metallic Nanoparticles
Published on: April 10, 2019
Oxidation of element 102, nobelium, with flow electrolytic column chromatography on an atom-at-a-time scale
Atsushi Toyoshima1, Yoshitaka Kasamatsu, Kazuaki Tsukada
1Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195, Japan. toyoshima.atsushi@jaea.go.jp
Abstract:
We report here on the successful oxidation of element 102, nobelium (No), on an atom-at-a-time scale in 0.1 M alpha-hydroxyisobutyric acid (alpha-HIB) solution using a newly developed technique, flow electrolytic column chromatography. It is found that the most stable ion, No(2+), is oxidized to No(3+) within 3 min and that the oxidized No complex with alpha-HIB holds the trivalent state in the column above an applied potential of 1.0 V.
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