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In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
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Related Experiment Video

Updated: Jun 22, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
11:03

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids

Published on: December 4, 2017

Nonperturbative approach to quantum Brownian motion.

Subhasis Sinha1, P A Sreeram

  • 1Indian Institute of Science Education and Research Kolkata, Mohanpur Campus, Mohanpur, 741252, India.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|June 13, 2009
PubMed
Summary

This study derives quantum Brownian motion equations from the Caldeira-Leggett model, revealing analytical expressions for diffusion constants. It shows classical Langevin behavior at high temperatures but finds positivity violations below a critical temperature.

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Last Updated: Jun 22, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
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Published on: March 30, 2017

Area of Science:

  • Quantum mechanics
  • Statistical physics
  • Condensed matter theory

Background:

  • The Caldeira-Leggett model is a standard framework for quantum dissipation.
  • Dekker's phenomenological model introduced anomalous diffusion terms in quantum Brownian motion.
  • Understanding quantum Brownian motion is crucial for various physical systems.

Purpose of the Study:

  • To derive quantum Brownian motion equations from first principles using the Caldeira-Leggett model.
  • To obtain analytical expressions for temperature-dependent diffusion constants.
  • To investigate the validity of Dekker's model and the positivity condition of the density matrix.

Main Methods:

  • Nonperturbative approach starting from the Caldeira-Leggett model.
  • Derivation of the master equation for quantum Brownian motion.
  • Analysis of diffusion constants at different temperature regimes.

Main Results:

  • Explicit analytical expressions for temperature-dependent diffusion constants were derived.
  • At high temperatures, anomalous diffusion terms are suppressed, recovering the classical Langevin equation and satisfying density matrix positivity.
  • At low temperatures, diffusion constants remain finite and positive, but the master equation violates Dekker's positivity condition below a critical temperature.

Conclusions:

  • The study provides a rigorous derivation of quantum Brownian motion equations, extending the Caldeira-Leggett model.
  • The findings highlight the limitations of Dekker's phenomenological approach at low temperatures.
  • The research offers insights into the temperature-dependent behavior and validity of quantum diffusion models.