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Mono- and terfluorene oligomers as versatile sensitizers for the luminescent Eu3+ cation
D Samuel Oxley1, Robert W Walters, James E Copenhafer
1National Energy Technology Laboratory, U.S. Department of Energy, Pittsburgh, Pennsylvania 15236, USA.
Abstract:
We present the design, synthesis, and physical and photophysical characterization of Eu(3+) and Gd(3+) complexes formed with two ligands bearing either one or three fluorene sensitizer units. As a novel sensitizing approach, the oligomer length is used to control the energies of the triplet states of the sensitizer and to mediate the sensitizer to lanthanide energy transfer.
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