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Related Concept Videos

IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations01:08

IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations

Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these vibrations also influence the shape of the IR peak. Generally, asymmetric stretching frequencies are higher than symmetric stretching frequencies. For example, primary amines exhibit two distinct IR peaks between 3300–3500 cm−1 corresponding to the symmetric and asymmetric N-H stretching, while secondary amines exhibit a single stretching vibration...
2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)01:19

2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)

Heteronuclear single-quantum correlation spectroscopy (HSQC) is a 2D NMR technique that reveals one-bond correlations between hydrogen and a heteronucleus. The HSQC experiment is similar to the heteronuclear correlation experiment (HETCOR) but is more sensitive. In the HSQC spectrum, the proton chemical shift is plotted on the horizontal F2 axis, while the 13C chemical shift is plotted on the vertical F1 axis. The corresponding proton and 13C spectra are also shown. The HSQC contour plot does...
IR Spectrum Peak Intensity: Dipole Moment01:20

IR Spectrum Peak Intensity: Dipole Moment

The dipole moment of a bond is the product of the partial charge on either atom and the distance between them. Dipole moments influence the efficiency of IR absorption and the peak intensity. When a bond with a dipole moment is placed in an electric field, the direction of the field determines if the bond is compressed or stretched. Electromagnetic radiation consists of an electric field component that rapidly reverses direction. It follows that polar bonds are alternately stretched and...
IR Spectrum01:19

IR Spectrum

When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's absorption spectrum, which is the plot of its percentage transmittance versus wavenumber.
Transmittance is defined as the ratio of the radiant power passing through a sample to that from the radiation's source. Multiplying the transmittance by 100 gives the percent transmittance (%T), which varies between 100% (no absorption) and 0% (complete...
IR Spectrometers01:25

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
IR Spectroscopy: Molecular Vibration Overview01:24

IR Spectroscopy: Molecular Vibration Overview

When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental vibrational motions that result in infrared absorption can be classified as stretching or bending vibrations.
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...

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A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
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Unambiguous chirp characterization using modified-spectrum auto-interferometric correlation and pulse spectrum.

B Yellampalle, R D Averitt, A J Taylor

    Optics Express
    |June 17, 2009
    PubMed
    Summary

    Modified-spectrum auto-interferometric correlation (MOSAIC) is a visual diagnostic for ultrashort laser pulses. Chirp ambiguity is resolved when the pulse spectrum is known, enabling complete pulse characterization.

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    Area of Science:

    • Optics and Photonics
    • Ultrafast Laser Science
    • Quantum Information

    Background:

    • Conventional second-order interferometric autocorrelation traces are used for ultrashort laser pulse analysis.
    • Modified-spectrum auto-interferometric correlation (MOSAIC) offers a sensitive and visual chirp diagnostic method.
    • Chirp ambiguity can arise in pulse characterization if the field amplitude or spectrum is unknown.

    Purpose of the Study:

    • To investigate the limitations and capabilities of MOSAIC for ultrashort laser pulse characterization.
    • To demonstrate the conditions under which MOSAIC can lead to chirp ambiguity.
    • To develop and experimentally validate a technique for unique chirp reconstruction using MOSAIC.

    Main Methods:

    • Construction of example pulse shapes with nearly identical MOSAIC traces.
    • Theoretical analysis of chirp ambiguity in MOSAIC diagnostics.
    • Development of a novel reconstruction technique combining MOSAIC envelopes and pulse spectrum information.

    Main Results:

    • Demonstration that MOSAIC alone can be ambiguous for chirp diagnosis without spectral information.
    • Identification of specific pulse shapes yielding similar MOSAIC traces, highlighting ambiguity.
    • Successful experimental demonstration of complete pulse characterization using the new technique.

    Conclusions:

    • MOSAIC is a qualitative tool for chirped pulses when spectral information is absent.
    • Knowledge of the pulse spectrum is crucial for unique chirp reconstruction with MOSAIC.
    • The developed reconstruction technique enables comprehensive ultrashort laser pulse characterization.