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Related Concept Videos

Potential Due to a Polarized Object01:29

Potential Due to a Polarized Object

A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
π Electron Effects on Chemical Shift: Overview01:27

π Electron Effects on Chemical Shift: Overview

An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0, resulting in...
Induced Electric Dipoles01:28

Induced Electric Dipoles

A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
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Molecular Shape and Polarity

Dipole Moment of a Molecule
π Electron Effects on Chemical Shift: Aromatic and Antiaromatic Compounds01:14

π Electron Effects on Chemical Shift: Aromatic and Antiaromatic Compounds

In aromatic compounds, such as benzene, the circulation of (4n + 2) π-electrons sets up a diamagnetic or diatropic ring current around the perimeter of the molecule. This current induces a magnetic field that opposes the external field inside the ring and reinforces it on the outside. The protons in benzene are deshielded and exhibit high chemical shifts in the range 6.5–8.5 ppm. The shielding effect at the center of the ring is evident in complex aromatic molecules, such as annulenes. In...

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Related Experiment Video

Updated: Jun 22, 2026

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

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Published on: September 5, 2019

Polarization effects in optically bound particle arrays.

Christopher D Mellor, Thomas A Fennerty, Colin D Bain

    Optics Express
    |June 17, 2009
    PubMed
    Summary
    This summary is machine-generated.

    Sub-micron polystyrene spheres self-assemble into 2D arrays using laser light. Particle arrangement is controlled by laser polarization, leading to diverse array structures like hexagonal and rectangular patterns.

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    Published on: June 28, 2018

    Area of Science:

    • Physics, Optics
    • Materials Science, Nanotechnology

    Background:

    • Sub-micron particles can self-assemble into ordered structures.
    • Laser light can be used to manipulate and trap particles (optical trapping).
    • Interactions between trapped particles (optical binding) can influence assembly dynamics.

    Purpose of the Study:

    • To investigate the effect of laser beam polarization on the self-assembly of sub-micron polystyrene spheres.
    • To characterize the different two-dimensional (2D) array structures formed.
    • To understand the interplay between optical trapping and optical binding in array formation.

    Main Methods:

    • Utilizing counterpropagating laser beams to create an evanescent field at a silica-water interface.
    • Employing polystyrene spheres with diameters ranging from 390-520 nm.
    • Observing and analyzing the self-assembled 2D arrays using optical microscopy.

    Main Results:

    • Observed spontaneous formation of 2D arrays of polystyrene spheres.
    • Identified diverse array symmetries including rectangular and three types of hexagonal arrays.
    • Documented a defective array with a missing every-third-row pattern.
    • Demonstrated that optical binding can dominate optical trapping, leading to incommensurate arrays.

    Conclusions:

    • Laser polarization is a critical parameter controlling the symmetry and dynamics of particle arrays.
    • Both optical trapping and optical binding forces govern the self-assembly process.
    • Complex array structures, including those not matching the laser interference pattern, can arise from particle-particle interactions.