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IM-19: a new flexible microporous gallium based-MOF framework with pressure- and temperature-dependent openings
Gérald Chaplais1, Angélique Simon-Masseron, Florence Porcher
1Equipe Matériaux à Porosité Contrôlée (MPC), Institut de Science des Matériaux de Mulhouse (IS2M), LRC CNRS 7228, Université Haute Alsace, ENSCMu, 3 rue Alfred Werner, 68093, Mulhouse Cedex, France. gerald.chaplais@uha.fr
Physical Chemistry Chemical Physics : PCCP
|June 25, 2009
Abstract:
Five metal-organic frameworks (MOFs) based on the same three-dimensional gallium terephthalate network (IM-19) are described, and an incommensurate structure (for the as-synthesized form) as well as two remarkable guest-free polymorphs (open and closed) are highlighted.
