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Published on: November 12, 2014
Formation of two- and three-dimensional hybrid mesostructures from branched siloxane molecules
Shigeru Sakamoto1, Atsushi Shimojima, Keiichi Miyasaka
1Department of Applied Chemistry, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169-8555, Japan.
Abstract:
We report the design of a new precursor having three branching disiloxane units capable of forming 3D mesostructures with a cubic Pm-3n and its orthorhombic and tetragonal variants Cmmm and P4(2)/mnm, in addition to a conventional 2D hexagonal (p6mm) mesostructure, thus creating a novel research area of mesostructural design in silica-organic nanohybrid materials.
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