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Improving Infrared Spectroscopy Characterization of Soil Organic Matter with Spectral Subtractions
Published on: January 10, 2019
Soil emissivity and reflectance spectra measurements
José A Sobrino1, Cristian Mattar, Pablo Pardo
1Global Change Unit, Image Processing Laboratory, University of Valencia, P.O. Box 22085, Valencia E-46071, Spain. sobrino@uv.es
This study analyzed soil spectra from diverse global sites, comparing laboratory and field emissivity measurements. Results show high accuracy, with a root mean square error below 0.015, validating remote sensing techniques for soil analysis.
Area of Science:
- Geosciences
- Remote Sensing
- Spectroscopy
Background:
- Soil spectral properties are crucial for remote sensing applications.
- Accurate emissivity measurements are vital for thermal remote sensing of Earth's surface.
- Understanding mineralogical influences on spectral signatures is key.
Purpose of the Study:
- To analyze laboratory reflectance and emissivity spectra of diverse soil samples.
- To compare laboratory-derived emissivity with field measurements using advanced algorithms.
- To validate the accuracy of remote sensing-based emissivity retrieval methods.
Main Methods:
- Collected 11 soil samples from Europe, North Africa, and South America (2002-2008).
- Measured hemispherical reflectance spectra (2.0-14 µm) using Fourier transform infrared spectroscopy.
- Determined mineralogical phases via X-ray diffraction (XRD).
- Calculated emissivity using Kirchhoff's law and compared with field radiometer data (CIMEL CE312-2) processed with ASTER emissivity algorithm.
Main Results:
- Laboratory emissivity spectra were derived from reflectance measurements.
- Field emissivity was obtained using a thermal radiometer and the ASTER algorithm.
- A root mean square error typically below 0.015 was achieved between laboratory and field emissivity measurements.
- High correlation observed between laboratory and field emissivity data.
Conclusions:
- Laboratory spectral analysis provides reliable emissivity data for soils.
- The ASTER temperature and emissivity separation algorithm, combined with field radiometer data, accurately retrieves soil emissivity.
- This validates the use of remote sensing for characterizing soil surface properties globally.
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