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Microfluidic-based Synthesis of Covalent Organic Frameworks (COFs): A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
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Surface mediated synthesis of 2D covalent organic frameworks: 1,3,5-tris(4-bromophenyl)benzene on graphite(001),

Rico Gutzler1, Hermann Walch, Georg Eder

  • 1Department of Earth and Environmental Sciences and Center for NanoScience, Ludwig-Maximilians-University, Theresienstrasse 41, 80333, Munich, Germany. rico.gutzler@lrz.uni-muenchen.de

Chemical Communications (Cambridge, England)
|July 15, 2009
PubMed

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Structure of Benzene: Molecular Orbital Model01:18

Structure of Benzene: Molecular Orbital Model

According to the molecular orbital (MO) model, benzene has a planar structure with a regular hexagon of six sp2 hybridized carbons. As shown in Figure 1, each carbon is bonded to three other atoms with C–C–C and H–C–C bond angles of 120°. The C–H bond length is 109 pm, and the C–C bond length is 139 pm which is midway between the single bond length of sp3 hybridized carbons (154 pm) and sp2 hybridized carbons (133 pm).