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Updated: Jun 21, 2026

Seeded Synthesis of CdSe/CdS Rod and Tetrapod Nanocrystals
Published on: December 11, 2013
Second-harmonic generation and crystal structure of the diamond-like semiconductors Li(2)CdGeS(4) and Li(2)CdSnS(4)
Jonathan W Lekse1, Meghann A Moreau, Katie L McNerny
1Department of Chemistry and Biochemistry, 600 Forbes Avenue, Duquesne University, Pittsburgh, Pennsylvania 15282, USA.
Abstract:
The semiconductors Li(2)CdGeS(4) and Li(2)CdSnS(4), which are of interest for their nonlinear optical properties, were synthesized using high-temperature solid-state and polychalcogenide flux syntheses. Both compounds were found to crystallize in Pmn2(1), with R1 (for all data) = 1.93% and 1.86% for Li(2)CdGeS(4) and Li(2)CdSnS(4), respectively. The structures of both compounds are diamond-like with the tetrahedra pointing in the same direction along the c axis. The alignment of the tetrahedra results in the structure lacking an inversion center, a prerequisite for second-harmonic generation (SHG). A modified Kurtz nonlinear optical powder technique was used to determine the SHG responses of both compounds. Li(2)CdGeS(4) displayed a type I phase-matchable response of approximately 70x alpha-quartz, while Li(2)CdSnS(4) displayed a type I non-phase-matchable response of approximately 100x alpha-quartz. Diffuse-reflectance spectroscopy was used to determine band gaps of 3.10 and 3.26 eV for Li(2)CdGeS(4) and Li(2)CdSnS(4), respectively.
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