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Updated: Jun 21, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
N,N'-Bis(2-ammonioethyl)propane-1,3-diaminium tris(perchlorate) chloride
Hanna B Szcześniak1, Violetta Patroniak, Wanda Radecka-Paryzek
1Department of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland.
Abstract:
The crystal structure of the title compound, C7H24N(4)(4+).3ClO4-.Cl-, is mainly determined by electrostatic interactions between the charged species and a number of relatively weak N-H...O and N-H...Cl- hydrogen bonds. The rich structure of such hydrogen bonds creates infinite layers of ions extending along the [001] direction. The tetracation has the gttttttg conformation, similar to the single previously known example of such a cation. The presence of two different anions can be connected with the undecided competition between them, and some of the packing advantages of such a situation are found in the crystal structure.
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