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Updated: Jun 21, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Supramolecular J-aggregate assembly of a covalently linked zinc porphyrin--beta-cyclodextrin conjugate in a
Takayuki Kiba1, Hiroki Suzuki, Kiyotada Hosokawa
1Division of Biotechnology and Macromolecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan.
Abstract:
The aggregation behavior of the zinc porphyrin-beta-CD conjugate in a water/ethanol binary mixed solution was investigated. The spectroscopic data and the atomic force microscopy (AFM) image strongly suggest that a part of a Zn porphyrin is included in the beta-CD nanocavity of another ZnP-beta-CD conjugate at certain concentrations, leading to the formation of Zn porphyrin J-aggregates.
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