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Related Experiment Video

Updated: Jun 21, 2026

Small Volume (1-3L) Filtration of Coastal Seawater Samples
04:21

Small Volume (1-3L) Filtration of Coastal Seawater Samples

Published on: June 19, 2009

Scattering by pure seawater at high salinity.

Xiaodong Zhang1, Lianbo Hu

  • 1Department of Earth System Science and Policy, University of North Dakota, Grand Forks, ND 58202, USA. zhang@aero.und.edu

Optics Express
|August 6, 2009
PubMed
Summary

A new model accurately predicts seawater scattering using Gibbs function, extending previous salinity ranges. This model improves upon older methods, offering more reliable predictions for various oceanic conditions.

Area of Science:

  • Ocean Optics
  • Physical Oceanography
  • Thermodynamics

Background:

  • Seawater scattering is influenced by density fluctuations, which are thermodynamically controlled.
  • Existing models for seawater scattering have limitations in their salinity ranges.
  • Accurate prediction of light scattering is crucial for understanding ocean optical properties.

Purpose of the Study:

  • To develop a new model for seawater scattering based exclusively on Gibbs function.
  • To derive thermodynamic parameters associated with density fluctuation for scattering.
  • To validate the model's performance across an extended range of salinities.

Main Methods:

  • Utilized Gibbs function to derive thermodynamic parameters linked to density fluctuation.
  • Empirically determined Gibbs function from highly accurate thermodynamic variable measurements.

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Large Volume (20L+) Filtration of Coastal Seawater Samples
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Published on: June 18, 2009

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Last Updated: Jun 21, 2026

Small Volume (1-3L) Filtration of Coastal Seawater Samples
04:21

Small Volume (1-3L) Filtration of Coastal Seawater Samples

Published on: June 19, 2009

Large Volume (20L+) Filtration of Coastal Seawater Samples
05:58

Large Volume (20L+) Filtration of Coastal Seawater Samples

Published on: June 18, 2009

  • Compared model predictions with existing experimental data (Morel, 1968) and another model (ZHH09).
  • Main Results:

    • The new model shows good agreement with Morel's measurements (-0.6% at S=0, 2.7% at S=38.4).
    • Seawater scattering increases non-linearly with salinity; linear extrapolation can overestimate by 30%.
    • The new model aligns within +/- 2.5% with the ZHH09 model over the entire salinity range.

    Conclusions:

    • The developed model is expected to be valid for extended salinity ranges (up to 120 g kg(-1)).
    • Linear extrapolation of scattering based on older data can lead to significant overestimation.
    • The new model offers a reliable method for estimating seawater scattering, even at high salinities.