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Updated: Jun 21, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Asymmetric quintuplet condensation in the frustrated S = 1 spin dimer compound Ba3Mn2O8
E C Samulon1, Y Kohama, R D McDonald
1Geballe Laboratory for Advanced Materials and Department of Applied Physics, Stanford University, Stanford, California 94305, USA.
Abstract:
Ba_{3}Mn_{2}O_{8} is a spin-dimer compound based on pairs of S = 1, 3d;{2}, Mn;{5+} ions arranged on a triangular lattice. Antiferromagnetic intradimer exchange leads to a singlet ground state in zero field, with excited triplet and quintuplet states at higher energy. High field thermodynamic measurements are used to establish the phase diagram, revealing a substantial asymmetry of the quintuplet condensate. This striking effect, all but absent for the triplet condensate, is due to a fundamental asymmetry in quantum fluctuations of the paramagnetic phases near the various critical fields.
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