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Unprecedented trinodal four-connected FRL MOF based on mixed ligands
Peng Li1, Jiaying Lou, Yaming Zhou
1Shanghai Key Laboratory of Molecular Catalysis and Innovative, Materials, China.
Abstract:
The hydrothermal reaction of Zn(OAc)(2) x 2H(2)O, H(3)btc, and 4-bpo affords a novel trinodal four-connected frl topology coordination polymer, [Zn(4)(btc)(2)(4-bph)(H(2)O)(4)](n) x 2n(H(2)O) (4-bphH(2) is in situ synthesized) (1), which exhibits reversible two-step dehydration-rehydration.
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