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Updated: Jun 21, 2026

Chemical Vapor Deposition of an Organic Magnet, Vanadium Tetracyanoethylene
Published on: July 3, 2015
Magnetic alignment in solid state and temperature hysteresis in aqueous tetrahydrofuran solution for
Hideo Enozawa1, Masashi Hasegawa, Eigo Isomura
1Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan.
Abstract:
Tris(tetrathiafulvaleno)dodecadehydro[18]annulene-hexaesters have a multi-functionality that is very sensitive to small differences in the ester side-chain. Self-aggregation of the [18]annulenes in amphiphilic media such as THF-H(2)O (v/v, 1:1) either produce a fibrous structure or result in temperature hysteresis of the color and (1)H NMR signals. This temperature hysteresis in solution is due to both strong self-aggregation behavior and unique cluster formation in a binary solution of THF and water.
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