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Updated: Jun 20, 2026

Soil Lysimeter Excavation for Coupled Hydrological, Geochemical, and Microbiological Investigations
Published on: September 11, 2016
Feedbacks between hydrological heterogeneity and bioremediation induced biogeochemical transformations
A Englert1, S S Hubbard, K H Williams
1Earth Sciences Division, Lawrence Berkeley National Laboratory, USA. Andreas.Englert@rub.de
Understanding subsurface heterogeneity is key for effective in situ remediation. This study reveals how hydrological and geochemical factors influence contaminant transport and reactions during biostimulation.
Area of Science:
- Environmental Science
- Geochemistry
- Subsurface Hydrology
Background:
- Optimizing in situ treatments requires understanding mass transport and reaction patterns in perturbed subsurface systems.
- Subsurface hydrological and geochemical heterogeneities significantly impact biostimulated reactions.
Purpose of the Study:
- To develop and apply a procedure for analyzing spatial and temporal patterns of mass transport and reaction intensities.
- To investigate the influence of subsurface heterogeneity on biostimulation experiments.
Main Methods:
- Temporal moment analysis approach using a streamtube approximation.
- Analysis of time-lapse concentrations of bromide, acetate, iron(II), uranium(VI), and sulfate.
- Application to two successive field-scale biostimulation experiments over two years.
Main Results:
- Hydrological heterogeneity predominantly drives bromide and acetate delivery and sulfate reduction intensity.
- Geochemical heterogeneity primarily controls iron(II) reduction intensity.
- Uranium(VI) reduction intensity is influenced by both hydrological and geochemical heterogeneity.
- Feedbacks between heterogeneity and biogeochemical transformations, including precipitate formation causing clogging, were observed.
Conclusions:
- Subsurface heterogeneity plays a critical role in the success and interpretation of in situ remediation strategies.
- Biogeochemical transformations are complex and influenced by coupled hydrological and geochemical processes.
- Precipitate formation due to remediation can lead to operational challenges like clogging and flow path alteration.
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