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Controlling the charge transfer in phenylene-bridged borylene-amine pi-conjugated systems
Agnieszka Proń1, Gang Zhou, Hassan Norouzi-Arasi
1Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany.
Abstract:
Novel boron-nitrogen-containing pi-conjugated compounds 3,3'- and 4,4'-((2,4,6-triisopropylphenyl)borylene)bis(N,N-diarylbenzenamine) (1-2), m- and p-phenylene bridged to the boron center, respectively, have been synthesized and characterized. Optical studies by means of UV-vis absorption and emission measurements as well as DFT calculations reveal a different charge transfer behavior between the para series and the meta series at ground and excited states.
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